American Association for Aerosol Research - Abstract Submission

AAAR 31st Annual Conference
October 8-12, 2012
Hyatt Regency Minneapolis
Minneapolis, Minnesota, USA

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Estimates of Non-Ideal Effects on the Agglomerate Dynamics

WEONGYU SHIN, George Mulholland, Seong C Kim, Jing Wang, Jacob Scheckman, David Pui, Chungnam National University

     Abstract Number: 738
     Working Group: Aerosol Physics

Abstract
Several characteristics of silver agglomerates are not incorporated in existing models for agglomerate dynamics. Existing models assume chain-like agglomerates with open structure. Silver agglomerates can be aligned in the electric field and have necking between primary particles. Primary particles on silver agglomerates are polydisperse and the primary sphere size are variable. Estimates of these features on the agglomerate dynamics were computed as perturbations to the Chan-Dahneke agglomerate model. The variable primary sphere size effect results in the largest change from the idealized model with about a 10% increase in scaling exponents for both friction coefficient – number of primary particles (η) and mass-mobility diameter (Dfm). The second largest change is a 4% decrease in the exponent η and a 4% increase in the exponent (Dfm) from the alignment in the electric field. The effects of necking between particles and polydispersity of the primary particles are negligible for the two exponents. Adjusting the model by this amount provides a significant improvement in the agreement between the model and silver agglomerate measurements for the dynamic shape factor.

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012-0004006).