American Association for Aerosol Research - Abstract Submission

AAAR 36th Annual Conference
October 16 - October 20, 2017
Raleigh Convention Center
Raleigh, North Carolina, USA

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Marine Aerosol Organic Composition and Sea Spray Production Processes

LYNN RUSSELL, Raghu Betha, Savannah Lewis, Jun Liu, Patricia Quinn, Timothy Bates, Scripps Institution of Oceanography

     Abstract Number: 481
     Working Group: Remote and Regional Atmospheric Aerosols

Abstract
Organic functional group composition of marine aerosol particles associated with sea spray were measured for submicron particles during five open ocean research cruises: one in the northeastern Pacific and four in the northwestern Atlantic. Fourier transform infrared spectroscopy provides information about the functional group composition that represents the marine organic fraction more completely than is possible with techniques that measure non-refractory mass. Primary biogenic marine particles have measured compositions in these ocean regions that include approximately 50-70% hydroxyl groups and 10-20% alkane groups. The organic composition of atmospheric primary marine (ocean-derived) aerosol particles is nearly identical to model generated primary marine aerosol particles from bubbled seawater. This study evaluates the processes that link the organic composition to sea spray production using ambient measurements.