Abstract View
Predicting the Influence of Particle Size on the Glass Transition Temperature and Viscosity of Secondary Organic Material
MARKUS PETTERS, Sabin Kasparoglu, North Carolina State University
Abstract Number: 293
Working Group: Carbonaceous Aerosol
Abstract
Atmospheric aerosols can assume liquid, amorphous semi-solid or glassy, and crystalline phase states. Particle phase state plays a critical role in understanding and predicting aerosol impacts on human health, visibility, cloud formation, and climate. Melting point depression increases with decreasing particle diameter and is predicted by the Gibbs-Thompson relationship. This work reviews existing data on the melting point depression to constrain a simple parameterization of the process. The parameter ξ describes the degree to which particle size lowers the melting point and is found to vary between 300 and 1800 K nm for a wide range of particle compositions. The parameterization is used together with existing frameworks for modeling the temperature and RH dependence of viscosity to predict the influence of particle size on the glass transition temperature and viscosity of secondary organic aerosol formed from the oxidation of α-pinene. Literature data are broadly consistent with the predictions. The model predicts a sharp decrease in viscosity for particles less than 100 nm in diameter. It is computationally efficient and suitable for inclusion in models to evaluate the potential influence of the phase change on atmospheric processes.